Understanding the way your storage works is crucial, yes. But you ensure people understand it not by asking "Explain ACID to me" but by asking to design a certain system and observing them figuring out requirements and asking questions. You then ask follow up question about consistency and reliability, you probably even can ask about benefits of using transactions but I wouldn't because there's plenty of databases that can be used reliably that don't have transactions.
Life is more complex than ACID, that's it. Investigate if person understands life, not that they were able to memorise bunch of magic acronyms.
For the life of me I don't remember what SOLID is and I totally fail to parse any written explanation of liskov substitution principle but whenever I see code that violates those I immediately go "please don't do this, that'll cause problems in the future".