It's always fascinating to see otherwise bright and competent characters end up making such bewildering decisions outside of their professions. In Pontecorvo's case, he condemned his young children to spending the rest of their lives in Soviet Russia - at a time when Stalin was still in power, no less.
It seems his son Gil eventually became a successful physicist in his own right, but I couldn't find out how the others fared. Based on my own experiences with communism, I can't imagine it was preferrable to life in the West.