Nope. Neither can ź, ć, ś, ą or ę. You can, and people do write them as z, c, s, a and e when writing in a restriced character set, but that is not 'correct' and is not a bijection, ie. „półka” and „polka” mean two different things.
There's also the case of technically-same-sounding-especially-recently ż/rz and ó/u (whose replacement would let you get rid of two 'non standard' characters), but for historical reasons these are not interchangeable.