we use Concur (1500+ employees). not my cup of tea but the accounting people love it.
Things like any date discrepancies between the receipt and how it's entered on the report get bounced even if they're off by a day even though it's obvious and, pre-Concur, would have just been fixed in-house. Also random invocations of travel policies cause rejections rather than not just making a trivial connection. Simply not reading comments with respect to exceptions. Etc. I'm sure hundreds of hours of highly-paid people's time gets wasted.