Like the device it’s plugged into actually has to communicate and negotiate that it wants something higher.
Until then it’ll just be I think 5V and up to maybe 1amp? (5W)
But also USB-PD doesn’t start at 48VDC.
And it is constantly monitoring for shorts. So if you did manage to get shocked it would only be for milliseconds.
So if she can do that with her mouth, you have other things to worry about. (She’s an android, not some colorful euphemism).
https://www.edn.com/what-does-selv-mean-for-power-supplies/
I doubt the USB-C power negotiation feature is specifically a safety function, but as other comments have pointed out it makes the system even safer.
I haven’t looked at the spec, but I wonder if there is any functionality that prevents a power supply from applying 48V all the time. i.e. is it possible to deliver a functional charger that is not SELV and has no power negotiation?