Decline of the Western Roman Empire was, in fact, at least regional collapse of civilization. Cities almost disappeared or at least shrunk considerably, including Rome, which peaked at 1 million people under Augustus, but had only 20-30 thousand people in the Early Middle Ages; other cities of the WRE fared even worse.
Literate secular class, including Roman state bureaucracy, disappeared as well, and with it large scale planning, monetary economy, large construction projects or most of long distance trade. Only the Church still maintained reading and writing, but that was a very small group of people.
All of this may not fulfill your definition of collapse of civilization, but I believe that a Roman citizen of 2nd century AD, suddenly transported to the 8th century, would be aghast seeing what became of his former home. Even cattle shrunk to half its former size and crop yields diminished, as agricultural best practices were forgotten.