It's smaller or lower-skill/fad-chasing orgs that end up doubling down on non relational systems for as the primary data store, lured in money-for-free promises of "no schema needed" and "scales automatically".
Nonrelational datastores have a place, of course, but they tend to be much more niche/purpose specific in functional engineering orgs in my experience--to the point that an engineering group's ideas around relational databases (what can they be used for? Should they be the default option for new use cases? How far can they scale?) are an effective proxy for that group's skill level.
Lots of big companies use Redis, MongoDB, Cassandra, DynamoDB, etc. when those tools address a business requirement better than a relational database. I have not seen NoSQL databases replacing important relational databases, I have seen NoSQL databases used for specific business requirements.
Of course big companies do a lot of software development, so you're more likely to see a variety of languages and tools in a larger organization. That may or may not validate the tools some people in the organization choose. Many large companies still use COBOL.
The SQL vs. NoSQL debate got framed early on in terms of better and worse, old vs. new, which is unfortunate because it created ideological camps. Not every supposedly new thing is better than the old thing. Some NoSQL techniques predate relational databases, but no one younger than 50 has experience with what we did before Oracle and DB/2.
Choice of tools should match the requirements, not fads or anecdotes or personal preferences (or ignorance).
Look harder :-) Every single NoSQL vendor has examples of substantial "replace' projects.