While identiability typically is just a person running an experiment and saying "hey look these state values are unable to be recovered / estimated when I ran the algorithm". This is why I never understood why this analysis was very helpful as it isn't very useful outside of the specific experiment / motion / inputs used.
For example from [1] has these reasonably straightforward definitions.
Observability is a structural property of a control system dened as the possibility to deduce the state of the system from observing its input-output behaviour
Identiability is the possibility to identify the parameters of a control system from its input-output behaviour.
Parameter identiability is a special case of the observability problem.
[1] http://www.math.chalmers.se/Math/Research/Preprints/Doctoral...