The ocean and the atmosphere exist in an equilibrium there is a 'balance' of relative concentration of CO2. Because CO2 can dissolve in water as CO3 and HCO3 the concentration is skewed to a higher concentration in oceans. When we take out CO2 from the oceans we lower the relative concentration, so we shift it out of balance. So the entire ocean becomes the surface area for re-absorbing CO2 from the atmosphere to re-establish that balance!