If you wanted just that one song then iTunes was very much the most affordable, and accessible, way to legally buy digital music back then because it only charged you $1 for a song.
The only other alternatives where, often legally rather obscure, flatrate subscription models or buying the physical full album, which would usually have cost you at least $20+
Valve did something very similar with Steam: Very easy to use and it actually passed on the savings from digital distribution to the consumers by heavily discounting the prices of games.