>water on said exoplanets based on spectrography
Even though from a theoretical perspective it should be way easier and more reasonable to detect particular molecules on distant planets via spectroscopy compared than to detect things on the mind-blowingly minuscule scale of gravitational waves, I think distant spectroscopy might actually be more prone to error, or at least more prone to false positives.
Just speculating since I have zero expertise in this area, but part of it may be because light from all sorts of sources is reaching us all the time, while gravitational waves significant enough to be feasibly detected pretty much only come from the top percentile of the most energetic events in the universe.
I think if you can discern a gravitational wave-induced spacetime wobble at least once and infer the motion that could've caused it (e.g. black holes/neutron stars merging) and see it matches theoretical expectations, you may continue to have a lot of false negatives, but you probably aren't at high risk of future false positives.
Whereas with spectroscopy, there seem to be a lot of things that can cause both false positives and false negatives even if you do have many prior detections that you believe are accurate. For spectroscopy, both error rates should go down over time as technology and techniques improve, but it seems like it may potentially be an inherently more "murky" observation technique, even if it's far simpler and far less expensive than gravitational wave detection.
(Someone please correct me if I'm wrong about any of this, because there's a pretty good chance I am.)