Natural keys are everywhere. They are just less interesting than the relationships. My name is a natural key. It uniquely identifies my name. The wheels come off if you expect it to uniquely identify
me. But with natural keys that's never actually necessary.
When I buy a car they record my name, my date of birth, the time of the sale and some details about the car, such as the VIN, which is its name. That provides enough information to form a natural key to identify the sale.
At no point does a database actually have a concept of who I am really, only the relevant data points to satisfy its own relational model.
Any database that means to track information about people would be able to construct a natural key from my name, my mothers name and some information about my birth, such as the doctor, hospital and time.