Old electric cars are a raw material of the future
economist.com
economist.com
Lithium is valuable because extracting it from naturally occurring salt deposits is a lot of work. These salt deposits are mostly not Lithium. We are talking trace amounts here. To extract it, you have to process vast amounts of brine. Boil of the water, separate it from other materials, etc. That's a lot of work and energy. Recycling a battery with high concentrations of Lithium is probably a lot less work. For that reason, lithium is a lot more expensive than other materials.
Melting old ice cars to recover the steel is already a thing. The steel has a value. All you need to do is melt it and reuse it. So, we already have existing practices for recycling old vehicles and companies specializing in that. The only thing that changes is that those companies will be dealing with very valuable batteries as well. Lithium is of course quite a bit more lucrative than steel. If it works for steel, it's going to work a lot better for lithium. Because it has a lot more value.
Batteries do become depleted but the lithium never disappears, I guess simply put a reverse potential is no longer able to reverse the battery equation back to the energy storing state. Presumably because there is some third reservoir state that a potential cannot reverse (without delving into the chemistry).
Don't be mistaken into thinking that because a charger cannot reverse the battery reaction that the lithium itself is gone, or that there does not exist some completely unrelated process that can recover the lithium - separate from the immediate battery ecosystem
It certainly can, E=mc^2. But it's an incredible amount of energy for how much matter you get.
For example, a fission/fusion reaction doesn't make matter go away, but the amount of energy released is large enough to be measured as a loss of mass. When you discharge a battery, it also loses mass, but the amount is too small to notice.
If Lithium is chemically changed what prevents it being chemically changed back?
Batteries are sealed, if material does not leave than all the components used to make it are still inside the battery.
Thermodynamics. It is also tremendously difficult to get your gasoline back after you burned it, or to un-cook an egg.
It is not difficult to recover lithium from a battery, but in general do not assume that physical processes are easily reversed.
https://www.scientificamerican.com/article/turning-carbon-di...
The only reason it's not done is because already made gasoline is cheaper.
If the lithium has changed chemically, presumably the feasibility of changing it back depends on the nature of the change.
What happens in old batteries is the physical structure of the lithium metal is damaged so it does not function as well as a battery, but you can separate out the lithium from the old battery, melt it down and reform it into a new battery (or whatever else you want to do with lithium.)
So an oxidized metal isn't "a metal" on the macro scale, because it isn't metallic.
Note that I'm discussing failure of a cell, not slow degradation in its ability to hold a charge, which has a variety of causes including the one you sketched out.
If it's trivial, shouldn't lithium recycling have been profitable from the moment we started making lithium batteries?
I think proponents of this economic view of recycling often argue that you could mechanically shred/grind such post-consumer products into a big mess and think of it as a new type of high-density ore. It might take different refining stages, but they seem to have faith that industrial processing can be invented for these materials and that it ought to be less energy intensive than processing the very low density ores found in nature.
As I understand it, lithium crystals form inside the battery and eventually short the battery out.
The lithium moves between the anode and cathode to release/store energy. I think when it's locked up in a crystal it isn't free to move and reduces the battery capacity as well.
An EV battery pack does not contain a spectacularly high concentration of lithium. A state-of-the-art battery pack might by 2% lithium. That's higher than subsurface brines, but not miraculously high. Brine mining also throws off lots of valuable products other than lithium. You can get potash, boron, magnesium, and other valuable ores from the same brine, so it can be hard for recycling to compete economically.
Ten year ago brines were about all of lithium supply, but now they're about half. The byproducts of lithium extraction from brine are profitable, but not enough to make a big difference to the bottom line of the mining operation.
https://pubs.usgs.gov/periodicals/mcs2021/mcs2021-lithium.pd... from https://www.usgs.gov/centers/nmic/lithium-statistics-and-inf... says that it's about half and half brines and hard-rock mining at this point. Even the expansion in Australia, which is indeed huge, only brings Australia to less than half of the world's lithium supply (40 kilotonnes out of 82 kilotonnes in 02020). All mining outside Australia is from subsurface brines except for one mine in China.
2% is "miraculously high" if subsurface brines are your reference point, because they're usually around 0.05% and almost never as high as 0.2%. It's an orders-of-magnitude difference.
Lithium costs on the order of US$10k per tonne. Potash is about US$800, boron around US$400, and magnesium around US$2000. All of these are mostly extracted from brines.
Also: it's not like EVs don't have steel chassis. It's (very roughly) the engine block and transmission mass that gets replaced by a battery. Once you remove that battery, the vehicles recycle identically. The only question is about how effective battery recycling is or can be (and it's pretty good already!)
Regardless, aluminum is expensive to extract and refine, requiring a tremendous amount of energy. In terms of cost, on average aluminum is more expensive than steel.
Huh? The main reason is because Aluminium is expensive. The BWW i3 uses an Aluminium frame exactly because it reduces weight. https://www.marklines.com/en/report_all/Munro003_201710
A Tesla battery weighs about 500 kg and has about 10kg of Lithium (2%). The Lithium is worth about $130, whereas the battery costs more than $10,000. It's difficult to extract the trace elements of lithium from the thousands of individual cells honeycombed together in the battery, so there is no known way of getting at that Lithium via processes that are even comparable to the value of the lithium recovered. That's why no one does it.
A car, on the other hand, is 55% steel by weight, and there are relatively straightforward ways of getting that steel (no, the car is not "melted down". The steel components are melted after they are removed from the car). That's why steel in cars is recycled but Lithium in batteries is not.
The issue with recycling is the cost of extraction -- yes, catalytic convertors and old computers contain trace elements like platinum (maybe $2 per catalytic convertor) but extracting it is far too expensive. So merely the presence of an expensive element in a manufactured good does not mean it is economic to extract the element. In the vast majority of situations, it's not.
Catalytic converters can be worth $100s as scrap. They’re regularly stolen from parked cars.
Globally, the catalytic converter industry uses about 112 tons or platinum, 170 tons of palladium, and 21 tons of rhodium per year. And an individual catalytic converter uses 1-2g for a small car up to 12-15g in a big truck. (Elsewhere I've seen 3-7g as an average for a US catalytic converter.)
https://www.thermofisher.com/content/dam/tfs/ATG/CAD/CAD%20D...
So from what I can tell, an average catalytic converter contains about 5g of PGM's which works out at:
1.85g of platinum at $40/g = $74
2.80g of palladium at $95/g = $361
0.35g of rhodium at $900/g = $315
The Washington post reports that catalytic converter thefts are largely driven by the rhodium they contain (the price of which has gone up enormously because it is a byproduct of platinum mining and platinum itself is not currently worth mining.)
https://www.washingtonpost.com/world/africa/catalytic-conver...
However, the reporters have acquired considerably more knowledge of the issues than I had.
At that point I looked a bit into the hydrometallurgical processes that were available, enough to convince myself that there were no showstopper problems that would make recycling battery waste uneconomical. But I didn't know about the pyrometallurgical processes at all, and I found that aspect of the article very interesting. Nor did I know about the current business situation.
This is fundamentally false.
The entire issue of environmental pollution exists because, or when, reuse isn't profitable.
If new raw materials are cheaper than reusing, then capitalism will absolutely result in dumping old materials and increasing pollution.
Why would you think otherwise?
What "dumb regulations" are you referring to specifically?
Tons of things aren't profitable even with zero regulations. That's my entire point -- not profitable even before any regulations.
Though regulations also exist for some pretty important reasons -- like prohibiting cheap child labor, requiring worker safety protections, etc.
You seem to be assuming that it is cheaper to mine trace minerals than harvest from existing batteries.
Absent any domain knowledge regarding the cost of these two sources of lithium, neither of you can presume to be correct.
The only fundamental thing here is that, absent any external pressure, in a capitalistic system, we will see suppliers of lithium prefer the source that is cheaper for them to utilize.
This article has much better domain knowledge than what I was able to dig up at the time, though.
I don't think we're arguing past one another at all. The central point of my comment was that people often made the error that crazygringo made; I explained why it was an error. Then, crazygringo responded, reiterating the error. I think my comment was rather precisely targeted at his comment, even though I made it earlier.
This is not one of those cases, precisely because (refining from) new raw materials is not cheaper than recycling waste.
The "electrical vehicles by weight" looks pretty much like Tesla Model S breakdown.
Tesla is alone in choosing aluminium, while the rest of the industry goes with steel.
The engine block is the heaviest part in an ICE vehicle, but it's usually made of grey iron, and not really steel, with German cars some times using silicon-aluminium, or much rarely magnesium alloy.
The body (or unibody) of any modern car is far heavier, given that it has so many functions and safety features as part of its design.
The Tesla model 3 and model y are steel by the way.
Somebody better tell the F150 designers.
The poop fertilized plants, the plants were harvested, some of them were turned into bread, others fed a pig, and that's what you're eating. Some of the poop decayed and was released as gases into the air, which were then recaptured by the plants, by bacteria in the roots of soybeans, and by Haber-Bosch factories (confusingly also called plants) which made synthetic fertilizer to fertilize the plants further.
You are recycling your sandwich, made from poop, into more poop.
This is the reflection on the disgusting nature of food and its link to the interdependent arising of all things. Your existence is inextricably linked to the existence of the pig and the poop. They are not separate processes; they are different focuses in the same process.
(Though the atomic nuclei didn't originate in the poop; they were just passing through. But cobalamin molecules, for example, do originate in poop pretty often.)
>Half of all the elements that are heavier than iron—such as thorium and uranium—were thought to be made when neutron stars, the superdense remains of burnt-out suns, crashed into one another. Long theorized, neutron star collisions were not confirmed until 2017. Now, however, fresh analysis by Karakas and fellow astronomers Chiaki Kobayashi and Maria Lugaro reveals that the role of neutron stars may have been considerably overestimated—and that another stellar process altogether is responsible for making most of the heavy elements.
KING CLAUDIUS Alas, alas!
HAMLET A man may fish with the worm that hath eat of a king, and eat of the fish that hath fed of that worm.
KING CLAUDIUS What dost you mean by this?
HAMLET Nothing but to show you how a king may go a progress through the guts of a beggar.
If you count CO2 as “poop” the percentages rise but the fossils still are in the lead.
For reference, that’s a Futurama quote.
It seems like battery lifetime may be better than expected (except in arizona, especially if your battery doesn't have sufficient cooling). And there hasn't been a lot of reporting of this happening, I haven't seen many anecdotal reports either. Maybe, it's still too early.
This is a big (underreported) factor in CNG vehicles though, a lot of their fuel tanks are expiring now, and for at least some vehicles, it's not economical to replace the tank, and at least PG&E requires a safety report before authorizing people to use their stations, so that makes a car junk simply because you can't fuel it.
In future, we could have an effective way of mining landfill for resources. Some forms of recycling now are highly inefficient and it’s conceivable that we’d be better off utilizing landfill and recycling with better techniques later.
I expect you'll see increasing mining of tailings piles as things like gold extraction technology improves.
The thing is now you’re rewarding an industry for making a mess in the first place, which is a bad pattern.
This is pretty far from the truth. Rock is less chemically complex than living plants, animals, and fungi, it's true; but there's a long distance from "less than hundreds of millions" to "just a few".
The article explains how it's done in the case of lithium-ion batteries.
It is true that to the extent that you can reduce the admixture of other materials, you can reduce the costs.
> How do you plan to do this
The standard mining methods include roasting, oxidation, and reduction (pyrometallurgy); froth flotation; lixiviation; defecation; crushing and grinding (milling or comminution); screening; and agglomeration. More exotic methods, some of which are crucial to one or another method, include vacuum sublimation, electrolysis (molten-salt or aqueous), amalgamation, recrystallization, and fractional distillation. There are also processes that don't fit neatly into one of these categories, such as the Pidgeon process. There's a good outline at https://en.wikipedia.org/wiki/Template:Extractive_metallurgy.
Batteries obviously have a small (-ish) set of possible compounds and it should be economically feasible to recycle used batteries once there is sufficient volume that needs to be recycled. (I guess we're still at least a decade away but that remains to be seen... if it's sufficiently efficient, it could be cheaper to recycle than reuse older batteries).
I joke, but I do believe there will be "waste miners" at some point in the future.
See also my comment at https://news.ycombinator.com/item?id=27163590.