LPTHW looks like a great book and may be a much more thorough introduction to Python for someone who is committed to learning the language; these videos are not really focused on that demographic. LPTHW is great if you're already a programmer or go in knowing you really want to learn how to program; hopefully where these videos can succeed is bringing in new people who are mildly interested and getting them started while showing them how fascinating programming can be. One day, hopefully Khan Academy will have enough videos and interactive exercises that a programming education will be as thorough as LPTHW, but that doesn't happen overnight.