The only reason cell networks work is that the telcos pay big money for getting access, power, and backhaul to places up high. No amount of power increases, modulation gain, reflector aperture, software, or anything else you can think up is going to get around the lack of line of sight.
Unless a decentralized mesh network has enough money to do this it will only ever work in specific regions where single individuals or groups can pay $$$ and cover large areas. Like in Seattle where the mountainous coastal terrain is useful for hamwan's network, or in mega-cities like New York where residents have skyscraper roof access for p2p wireless community ISPs.