The last time I looked into this it seemed like US junk mail might be roughly the same CO2-scale as Bitcoin.
Which isn't an argument against killing Bitcoin for its contributions to CO2 emissions, mind you, but it seems another similar low-hanging fruit of generating a huge amount of waste to benefit a small number of people economically, while being extraordinarily simple to "just stop doing it". (As opposed to, say, fixing all building insulation in the US, which is a larger problem, and should be done, but is non-trivial to fix.)
With the added benefit that a hundred million people actively hate the existence of junk mail, so I think "we need to ban junk mail because global warming" has legs.