Firefox 5 can already be downloaded from Mozilla’s FTP server
mths.be
mths.be
But the truth is, the DOM and XPCom APIs are pretty stable and most upgrades don't truly break an extension. And FF makes it quite easy to do a "version compatbility update" that doesn't require a new version and new deployment but a lot of app developers just don't do this as quickly as we'd like.
Long story short, you can open up that install.rdf in each extension and set it to 5.x and give it a try. Worst case scenario, you disable that extension from safemode if it crashes your browser. But that's unlikey IME.