Killing SMS
rdicker.com
rdicker.com
This is not to say that this can't be a fantastic business - great barriers might mean that there's a mint to be made if you figure out a way around them - just don't underestimate the lack of cooperation from the carriers. That'll be your biggest showstopper.
I don't even think the network effects are that important. My girlfriend and I could use it to keep in touch with only each other without paying SMS fees during the day. Then we can tell another couple about it. Much the same happened with Skype and people using it to call their parents.