What makes you so sure there is really a binary divide between introverts and extroverts? Even if it shows up on tests, whose to say that's not a learned behavior?
Here's what I think: as a young kid, you get exposed to things that shape your attitude. If your early experiences are negative in social settings, perhaps you grow up to be introverted. But what happened first - your negative experiences, or an attitude that pre-disposed you towards negative social experiences? Can little little kids have attitudes like that? Hard to day - how do we really know?
I don't care what physical science has to say on it regarding brain maturity, neuro-pathways, etc - unless we can communicate with infants, we don't know if they have pre-disposed attitudes or thoughts.