The Extended Kalman Filter (EKF) relies on local linear linearizations to handle nonlinearity. This works for mildly nonlinear systems, but doesn’t do so well when the system is highly nonlinear (divergence happens).
The Unscented Kalman Filter (UKF) is a kind of particle-like filter but instead of propagating a large number of points, it only propagates carefully chosen “sigma points”. It’s much more economical and works relatively well with nonlinear systems.
To me, the gold standard in estimation is the Moving Horizon Estimator (MHE) [1] which solves an explicit optimization problem to arrive at the state estimate, which allows it to accommodate constraints in the system. It is however computationally much heavier than the Kalman family of filters.
I’ve implemented UKFs in the past and think they’re a good trade off between computational speed and accuracy in the presence of nonlinearities. They cannot handle constraints however, which is a major weakness that MHEs don’t succumb to. (Imagine you are estimating a quantity x in the interval [0, 1] - UKFs can return estimates like 1.32 or -0.3 whereas MHEs accommodate bound constraints like 0 <= x <= 1 as well as more complex constraints to prevent weird outputting impossible or weird state estimates)
[1] https://murray.cds.caltech.edu/images/murray.cds/0/0d/L4-2_M...