Sound waves that we perceive as tonal -- as musical -- commonly consist with partials which follow a certain pattern. Namely, there is one lowest partial, and most or all of the higher partials have frequencies which are INTEGER MULTIPLES of the this lowest partial's frequency. For example, if the fundamental is at 200Hz, perhaps the next lowest partial is at 400Hz, and the next one might be at 600 or 800Hz, and so on.
When partials are organized like this, they are known as HARMONICS. The lowest such partial -- the lowest harmonic -- is called the FUNDAMENTAL, and the remaining (higher) harmonics are known as the OVERTONES. It is common, but not always the case, that the fundamental (1) defines the pitch of the sound (2) is the loudest harmonic. Overtones instead tend to add color to a sound.