The top health problem is mental health. I believe many of them came from the fact we should work to live.
Table 2-3 shows the breakdown of "health problems," and depression is at about 40%. Even if all of those were due to overwork, this is only 40% of the "health problems" category, which is not enough to support a claim that "most suicides come from excessive work." For sure, there may be many cases that do, but there are no clear numbers in that regard. Personally, I feel such claims only reinforce the typical stereotypes about Japan rather than try to understand the actual situation.
I was thinking more on the root causes of those health problems, which might or might not be work related, that's just a belief of mine (that's why I provided no sources and wasn't very assertive)