Edit: Ok it turns out there's 2 parts to a cooling roof, how reflective it is, and how good it is at emitting infrared radiation (emissivity). Reflectivity of visible and UV light prevents more energy from being absorbed, but doesn't necessarily mean the material cools down well once hot. A high emissivity means the material can cool down quickly through radiation.
I guess YInMn blue has a high emissivity.
https://en.wikipedia.org/wiki/Reflective_surfaces_(climate_e...