Big people burn more calories even when still. Active people burn more than still people of the same size. Muscular people burn more calories than the non-muscular as they have to feed their bigger muscles.
In sealed room tests fat people use more calories than thin people.
Skinny people who can eat anything they want without putting on weight tend to be very fidgety - they never keep totally still. Just wiggling a leg all day can use a large amount of energy.