I think Adam's approach is mostly lacking deliberation, it's only after the fact that the synergy is realized but it's hard to intentionally engineer it.
I can definitely see the validity in the other school of thought though; i.e. that we should deliberately seek out synergistic talent verticals. I know this is Conor Mcgregor's approach, he's very much systems over goals (in Adam's vein, and explicitly so) but is deliberate about the specific talent stack he's working towards. Ironically it is all done towards a specific goal (to be the best fighter) although the path towards that goal is underspecified.
Here's a very common talent stack here on HN that works pretty well: math + CS + data science + one domain (e.g. finance or biology).