I really want to talk to people building piles of spaghetti on noSQL because "it scales". At some point you've just go to start tearing your hair out.
Postgresql can do 1.5M queries (read/write) per second on OLTP loads on one box just to get started. If you really need more you can get extremely high with replicas. Then application design comes into play.
I'm tired of folks picking "noSQL" so things can scale. Dealing with all the edges cases as these things scale is a nightmare (plug mongodb and friends seem to fall over MUCH more often, recovery is miserable with them etc).