To the best of the reasearchers' knowledge: All known pathways to produce phosphane couldn't explain the observation (they were talking several orders of magnitude off). Abiotic 'exotic' chemistry is still an option (ie the 'unknown unknown' hasn't been ruled out).
It's impossible to rule out an "unknown unknown" by definition, because if you did then it wouldn't be "unknown" anymore.
That's K-K, not U-U.
There are unknown biotic pathways known to exist (from the press conference, biotic phosphane production on earth apparently still has some large question marks attached?).
There might be unknown abiotic pathways ('unknown unknowns'). In principle, there could be some clever way to rule them out based on the constraints of the Venusian environment.
A sample of aliens can help leapfrog our understanding of biology, just like the study of terrestrial bacteria allowed us to precisely edit genes. Really interesting things happen biologically in extreme conditions.
(This estimate assumes that tidal forces are proportional to 1/R^3 and that the orbital radius of Venus is 73% of Earth's)
They were pretty clear in stating up front they have not ruled out abiotic processes, and are not declaring that they have discovered life. They state based on the known conditions of Venus and known chemical pathways to phosphine, and what is known about phosphine as a bio-marker, that life is a distinct possibility.
Through further research either we'll learn something new about Venus, phosphine production (which could improve our understanding of its relevance as a biomarker in the universe), or confirm some form of biological process.