Path loss through free space at these relatively low frequencies (<6 GHz) isn't from air/water vapor losses. It's from diffraction spread.

This company can say all they want about near field tech, but the beam waist diameter relative to wavelength determines the diffraction spread. And that aspect of path loss is proportional to the distance in wavelengths even if there's no "absorption" by the air components. For any reasonable link at 2.4-5.8 GHz the length in wavelengths will be tens of thousands.

Instruments that sweep all frequencies have been available since shortly after the dawn of radio and public atmospheric absorption tables have been available for nearly as long. Also, absorption bands tend to be very broad in this region, so after 10 or 20 data points there's nowhere for a magic frequency to hide.