Uhh if you need 25 more people that tells me that your code is less maintainable and you're writing much more of it. No one has ever debated that in raw execution speed Java is faster, the problem is that most startups have plenty of CPU and few devs.
Twitter really did things ideally, start on a rapid dev platform and then port to a faster platform after acquiring the userbase and capital infrastructure that makes such a decision make sense. I'm not sure that if I was working on the JVM that Java would be my language choice, I'd probably use Mirah/Clojure/Scala.
The extra 25 devs are probably to ensure T2EE (Twitter 2 Enterprise Edition) compliance and refactor their POROs (Plain old ruby objects) to work with their ETB middleware. /snark