Going to heavily disagree here. Whether or not your user's will notice is debatable in itself, but you shouldn't really factor that into your decision making.
Instead you should ask if your users would care that it uses Electron, and more whether they would be sufficiently put off to look for alternatives. And in a vast majority of cases the response to that question is going to be 'No'.
But the second part of this comment, I disagree with even further. DO NOT USE A NATIVE WEBBROWSER CONTROL FOR YOUR DESKTOP APP's UI.
Sorry for yelling, but that really is that terrible an idea. Most native webview components lag behind the embedded chromium instance Electron uses by a lot. Basic things that would work in IE10 are known to break on desktop webviews. Primary reason for this is that these webviews are only updated with OS updates.
End result is you will have to bend over backwards to get your UI working as expected on all these native webviews. This is just too much work and will end up diverting attention from developing core features of your app to fixing rendering bugs instead.