Some really good screencasts are needed to show what's possible with appCode - fortunately JetBrains does excellent screencasts for their other products and I'm sure they'll do these as it gets closer to release.
As for me, I'm a long-time IntelliJ user. Xcode 3 has been incredibly painful to use - even after taking a lot of time and effort to learn the keyboard shortcuts.
Xcode 4 is a major step in the right direction and started to actually make iOS coding reasonably fun. But it still can't hold a candle to the features available in this early release of appCode - it's awesome.