The reason dual hose are more efficient is mainly that single hose portable A/Cs pull the air used to cool the radiator and compressor (and expel hot air outside) from the same room they're cooling.
That air has to come from somewhere, so it's going to pull warm air from everywhere it can, door, windows, any creaks/holes/openings, etc. And the fans have some serious airflow/CFM.
Dual hose designs pull air from outside and expel it back outside.
So technically it should be capable of getting your room colder and keeping it that way with less compressor usage.
The cold part of the A/C just circulates air around the room on any model.
Looking at my model, I could turn it into a dual hose design - it pulls air from the rear, right below the exhaust vent. That seems to be the case for a lot of these. Creating an attachment/adapter to connect another hose seems easy enough.