> An expression used inside a grouping_element can be an input column name, or the name or ordinal number of an output column (SELECT list item), or an arbitrary expression formed from input-column values. [0]
> Each expression can be the name or ordinal number of an output column (SELECT list item), or it can be an arbitrary expression formed from input-column values. [1]
Perhaps you are thinking of trying to use an output column name in a WHERE clause?
[0]: https://www.postgresql.org/docs/current/sql-select.html#SQL-...
[1]: https://www.postgresql.org/docs/current/sql-select.html#SQL-...