I would guess that at most water has been drunk multiple times, but that there is some miniscule a fraction that moved between icecap, permafrost and deep water table and has avoided being consumed by an animal since it arrived on earth.
I would be interested to read a mathematical estimate of how many 9s of water on earth has been drunk at some point.
https://www.sciencefocus.com/planet-earth/are-we-really-brea...
Lets say the average human drinks 3 liters per day and lives 80 years (3 * 365 * 80 ) = 87,600 liters per human.
there have been about 100 billion humans so 100 b * 87600 =8,760,000,000,000,000 liters have been drunk.
there are about this many liters in Earths 5 oceans (source google search): 1,400,000,000,000,000,000,000
Assuming no one has ever drank the same amount of water before, 8,760,000,000,000,000 < 1,400,000,000,000,000,000,000
It sounds fairly certain that not all water has been drunk by a human, even if my math is way off