I worked on a pilot project with a state government group that wanted remote monitoring of water levels in wetlands and ponds spread across a few hundred square miles of mostly-rural area. wi-fi obviously wasn't an option and getting a WAN mesh setup was a huge pain in the ass and had its own limitations. We ended up testing with 3G, switching on twice a day to report, but the power consumption and data costs were too prohibitive to be practical long-term. 5G power use per bit is supposedly going to be far lower than 3G/4G. Jury is still out on data cost.
I now work in the automotive industry where vehicle logistics can be an interesting challenge. Parking lots for completed vehicles awaiting transport outside factories can be spread across a square mile of land (more if remote overflow lots are used), with multiple locations. There are multiple use cases for inspecting, tagging, remote driving, etc. these vehicles using aerial or ground-based drones and teleoperation to significantly cut down on costs. However, those use cases depend on high bandwidth, low-latency connections and extending effective wi-fi to lots would be massively expensive. 5G is a pretty interesting option here.
As others have mentioned, vehicle-centric use cases abound, but there are some additional ones for industries like oil & gas as well.