Yes, but people have to eat and try accounting for per 1000 w/m^2 of sunlight over crop and grazing land, after adapting for food production in tunnels with LEDs. Or trying to figure imagine what transportation looks like. Easier to just look at current usage and accept it's a spitball estimate. For cubes, what building material available there will support 3-d structures at that scale? It's mostly ices out there. Relying Ni/Fe asteroids feels like magical thinking and is not in line with scales involved. For that mater, where's all the carbon going to come from to make the people out of?
For reference, if you assume 1000 sq ft per person (maybe generous, but you have to account for transportation conduits, plumbing, food production, structural reinforcement) with 10 ft height, it's about 300 cubic meters. For a trillion people, that ends up being a 70km cube. I doubt there is any durable foundation on Pluto, and any structure would melt the ground it's (axiomatic thermodynamics) without active cooling, which increases the energy requirements.
Ultimately, I don't see why anyone would want to live packed into a small cube on Pluto eating engineered food. A trillion people packed in a cube underground in a block of gas ices isn't going to experience wonder and joy of exploration.