I don't really follow this.
The fact that the linking exception and the LGPL exist at all is enough to infer that the FSF/license authors consider linking against or otherwise using a piece of software as a component of a larger system is enough to make that larger system a derivative work of the smaller component, thus "tainting" (I use this work non-disparagingly) it with the copyleft provisions of the license.
If Google Maps (that is the suite of software running on Google's servers) uses PostGIS as its data store then it seems that without a judicial ruling on whether there's a legal difference between interfacing with a software component by linking against it and interfacing with a software component by using some other software interface, it's not possible to be so certain that there isn't an issue here.