Boiled skin-on potatoes are good; complex carbs, Vitamin C and B6, potassium, fibre, water, but maybe lacking in hipster value.
Simple carbs are great for physical activity in proportionate amounts, but fairly terrible otherwise.
When I had a heavy manual job I'd come home, have a cold beer then knock back a litre of orange juice, probably containing 100g/4oz of sugar. Seemed to go to muscle glycogen though occasionally I'd rush :-)