https://onlinelibrary.wiley.com/doi/abs/10.1002/adma.2020027...
attempts to mimic the performance of the leading lithium-ion battery cathodes, nickel-manganese-cobalt (NMC) and nickel-cobalt-aluminium (NCA) by carefully synthesizing the cobalt-free hybrid nickel-manganese-aluminium (NMA) to mimic the crystal structure of NMC and NCA. In all cases, the largest fraction of the cathode is nickel, and cobalt/manganese/aluminium are essentially dopants. The authors note that manganese and aluminium produce opposing effects on the crystal structure of lithium-nickel-cobalt oxides, and go on to say:
>Strikingly, a natural combination of Mn and Al in high-Ni layered oxides, i.e., LiNi 1−x−y Mn x Al y O 2 (NMA; suggested by us earlier [8] ), has not been reported to our knowledge.
It is definitely surprising that the missing "third leg" between NMC and NCA has not received more serious attention, if that is true. Manganese and aluminium are both far more common than cobalt.