If you become familiar and known in the scene the risk of being scammed is very low and if it happens it's more like a "one last money grab and I am done thing" where the person offering the service will disappear. But since this works once per online persona this really doesn't happen that often.
Not that I'm planning to purchase any of those services of course, I'm just curious because it sounds like there's no possible starting point, unless by pure chance one of your personal friends happens to be already involved in the area and lets you know.
Use the phrase "darknet" then just apply the word "markets" and you'll already started the jump down the rabbit hole.
For more mundane services, though, most 'darknet markets' like Silk Road have a seller account reputation system, like ebay; and a payment escrow system. So you can choose a seller who has 100 previous transactions and a 99.5% positive reputation. And if they don't deliver, they don't get paid.
You can also ramp your purchases up gradually, buying the $10 1-hour DDOS and the $60 1-day DDOS, thus confirming the supplier can deliver before spending more than you can afford to lose.
And of course it's traditional for every bitcoin/darknet service to eventually fold with some insider making off with everyone's money. For that, I don't know what the common mitigations are, apart from not carrying an account balance larger than you can afford to lose.
[1] https://www.theguardian.com/technology/2013/nov/21/silk-road...
https://www.usenix.org/system/files/conference/woot16/woot16...
It uses the outputs of the key exchanges as proof that the attack was carried out. I doubt anyone uses it in practice though.
If you're in a "law enforcement free-zone" and can bank a recurring service fee versus a one-time scam running these kind of services, why not engage in such behaviour?
There are career criminals with reputations also.