Lower / more diversified risk doesn't necessarily mean more liquid. For every big liquid ETF, there's many smaller ETFs with similar holdings and thus similar diversification and risk, but much lower volume, wider spreads, shallower order books, etc.
Though I agree that long-term, smart investors will prefer to own a diversified product because of that lower risk. So it does make sense that whatever diversified product they choose becomes more liquid than its constituents, just for the small number of winners they coordinate on (thanks to better marketing, lower fees, better deals with market makers, etc.) and not all ETFs with comparable risk profile.