If by application database you mean to the level of an RDBMS then no. It's a key-value data store. You get your CRUD operations, expiry, key listing and the ability to do pagination with keys always returning in lexicographically sorted order. Any relation data you want to have would be using the key prefixes, e.g.:

  article:1 -> {"user": 1, "content": "..."}
  user:1 -> {"name": "username"}
  user:1:articles -> [1, ...]