When I worked in a large bank we tried to migrate core system from Db2 zOS to Postgres and it went nowhere. I was a in-house developer working with Postgres consultants and they were amazed by db2 performance in OLTP scenarios.
So if your organization is already spending cash on Oracle, Db2 or MSSQL, use them for superior performance. Migration off them is costly and risky process.
If your working at a startup there is absolutely no reason to choose anything but Postgres if you need relational.