Some people certainly do have a natural talent for something. However, this rarely means that they're good enough to succeed at that thing without working on it. I.e. if your ex wanted to make a living as an artist she'd still likely have had to go to school / practice extensively before being good enough that people would have bought her stuff.
Also, and I don't know whether this is the case with your ex, it's entirely possible that she was better at art because she'd been idly drawing over the years. I've certainly known people who wouldn't call themselves artists whose default idle activity is to sketch away on a piece of paper. They're vastly better than me, because they've been practicing in a low-key way for years.
Natural talent just gives you a head start on others. Someone willing to put in more effort than you can still be better than you.
I suppose this may break down around the limits of a field, especially one rooted in physical activity. E.g. Michael Phelps seems to be nearly perfectly physically adapted for swimming. If he never practiced then he'd be easily outswum by anyone half-decent... but by putting in massive effort training he reaches a point where he's practically unbeatable.