people who are very good at C or C++ will be able to learn Rust pretty quickly yes.
People who LIKE C probably won't like Rust though. Its more like C++.
IMO, Rust shares the same inner-simplicity that C has, but combined with ability to build and use bulletproof higher-level abstractions. The same way I roughly knew what machine instructions (roughly) my C code produces, I know what machine instructions my Rust code produces.
It is the equivalent of C++, not C. You can write code which you cannot guess the machine code, as soon as you use any of the abstractions, just like C++.