Take them off during the daytime. They're not permanent installments.
But yeah shutters or something smarter (like two-state glass) should work IMO. I think you even get glass that can switch to mirror mode.
That would be crazy-expensive. A lot of greenhouses use poly-film, to give you an idea of the budget. Replacement cost is a large factor.
A variation of that only catches the sun’s green light and uses it to power pink/red LEDs (https://www.treehugger.com/solar-technology/solar-smart-gree...)