I don't think it's a good idea to wait for such undeveloped technology to mature, because the clock is already ticking. It is still much more important to reduce emissions now.
What would be much better, for example, is developing smaller cars. I would rather see society organize for a voluntary reduction of co2, because capturing co2 seems like scientifically too fastidious.
Also, I'm european and I tend to be very pessimistic when looking at US co2 emissions per capita.