You can make a backup by saving in some safe place a copy of the QR code and/or the 16 character text code Paypal gives you to set up your TOTP device.
You can then use that later to set up a replacement TOTP device if something happens to your first one.
I usually use "grab" on my Mac to save a copy of the QR code as a PNG, encrypt that, and save it in an offsite location.
Another popular approach is to print the QR code and save the printout in a fireproof sale. If you do that, I recommend printing it before you use it to set up your first device, and then set up the first device from the printed code just to make sure the printed code is fine.
If you save the text code, you can also use that with oathtool from oath-toolkit [1] to generate the TOTP code on the command line if you need to use Paypal before you have your replacement TOTP device.
Note: if you do want to have two TOTP devices set up at the same time, there are two ways to do this with Paypal. One way is just to scan the same code in both devices. You can either set them both up at the same time, or add the second one later using the backup you made of the original code.
The other way is to go to Paypal's security settings and explicitly say you want to add a backup TOTP. It will then give you a QR code to scan. That is not the same code as it gave you for the first device. The codes generated from the second device initialized from that second code will not be the same as the codes from your first device.
I have no idea what the user interface is for logging in when you have two devices generating separate TOTP sequences. Does it expect you to use the first device, and if that fails ask you to try a backup? Or does it just accept codes from either? Or something else?
Offhand, I can't think of any compelling reason to prefer your two devices to have different codes, or for Paypal to need to know that you are using two devices. Just setting them up with the same code and letting them appear to the be the same device as far as Paypal is concerned seems simpler to me.
[1] https://www.nongnu.org/oath-toolkit/