Highly sensitive tests are great for this. They're usually cheap and quick. They have a low false positive rate so a negative result is likely to be correct.
Since they detect anything that even remotely looks like the targeted substance, they have a substantial false positive rate and a positive result must always be confirmed with specific tests. However, police forces seem to treat a positive result as sufficient cause for an arrest.
https://www.ncbi.nlm.nih.gov/m/pubmed/12423006/
Without confirmation, false positive rates varied from 2 to 4 percent.