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I worked in a semweb shop for ages, it's all over government where machine interoperability is key and also in complex data areas like pharma.

Cool! Makes sense. What are some good examples on the govt side?

http://www.data.gov/communities/node/116/apps - the data integration being done here is all driven by semantic web, linked data and RDF.

http://data.gov.uk/apps - same thing here, driven by the semantic web and linked data.